In a recent paper, Brlek, Jamet and Paquin showed that some extremal infinite smooth words are also infinite Lyndon words. This result raises a natural question: are they the only ones? If no, what do the infinite smooth words that are also Lyndon words look like? In this paper, we give the answer, proving that the only infinite smooth Lyndon words are m_{a<b}, with a,b even, m_{1<b} and Δ^-1₁(m_{1<b}), with b odd, where m_A is the minimal infinite smooth word with respect to the lexicographic order over a numerical alphabet A and Δ is the run-length encoding function.